• 超干溶剂
  • HPLC气相顶空
  • HPLC
  • LC-MS
  • 卡尔费休冠军国际cmp
  • 当量溶液
  • 电导率标准溶液
  • pH缓冲液
  • 农残溶剂
  • 原子吸收标准溶液
  • ICP标准溶液
  • 阴离子标准溶液
  • 无机盐
  • 其他
  • 离子对冠军国际cmp
  • 稳定同位素
  • 紫外-可见吸收光谱
  • 品牌 Scharlab
  • 编号 AM03200050
  • 规格 eluent additives for LC-MS
  • CAS  540-69-2
  • MDL Number  MFCD00013103
  • 包装 价格 库存 - 促销价
    50g     
    RMB     0
    Ammonium formate, eluent additives for LC-MS	甲酸铵,LC-MS添加物

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  • Mol. Formula: HCO2NH4
  • Mol. Weight: 63.06
  • Melting Point: 119-121
  • Density: 1.26
  • TSCA: Yes
  • Solubility: 可溶
  • Stability: 易吸潮
  • Appearance: {Chemicalbook} 无色结晶,熔点11...
  • Chemical Name
    Ammonium formate
    CAS Number
    540-69-2
    PubChem Substance ID
    24873910
    MDL Number
    MFCD00013103
    Synonym
  • 甲酸銨
  • Ameisensäure Ammoniumsalz
  • AMMONIUM FORMIATE
  • AmmoniumFormateAr
  • AMMONIUM FORMATE PURE
  • 甲酸铵盐
  • FORMIC ACID, AMMONIUM
  • AMMONIUMFORMATE,CRYSTAL,REAGENT
  • AMMONIUM FORMATE
  • Ammoniumformate,99%
  • AMMONIUM FORMAT
  • Formic acid, ammonium salt
  • 甲酸铵 溶液
  • 甲酸铵
  • EC Number
    208-753-9
    Merck Number
    14,523
    Beilstein Registry Number
    3625095
    Chemical Name Translation
    甲酸铵
    Wiswesser Line Notation
    VHO &ZH
    GHS Symbol
    WGK Germany
    1
    Hazard Codes
  • Xi
  • Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • Personal Protective Equipment
  • dust mask type N95 (US), Eyeshields, Gloves
  • Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
  • Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • Signal word
  • RTECS
    BQ6650000
    Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • Storage condition
  • Store at RT.
  • 密封干燥保存。
  • Hygroscopic
  • TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
    ROUTE OF EXPOSURE       : Oral
    SPECIES OBSERVED        : Rodent - mouse
    DOSE/DURATION           : 2250 mg/kg
    TOXIC EFFECTS :
       Details of toxic effects not reported other than lethal dose value
    REFERENCE :
       ZERNAL Zeitschrift fuer Ernaehrungswissenschaft.  (Dr. Dietrich Steinkopff
       Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.)  V.1- 1960- 
       Volume(issue)/page/year: 9,332,1969

    TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
    ROUTE OF EXPOSURE       : Intravenous
    SPECIES OBSERVED        : Rodent - mouse
    DOSE/DURATION           : 410 mg/kg
    TOXIC EFFECTS :
       Details of toxic effects not reported other than lethal dose value
    REFERENCE :
       ZERNAL Zeitschrift fuer Ernaehrungswissenschaft.  (Dr. Dietrich Steinkopff
       Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.)  V.1- 1960- 
       Volume(issue)/page/year: 9,332,1969

  • 分析冠军国际cmp,从贵金属盐中沉淀碱金属。 缓冲液组分,用于在凝聚胺(polybrene)亲和层析从复杂系统中分离和纯化糖胺(glycosaminoglycans)
  • Merck:14,523 Beilstein: 2,IV,18
  • Reagent for N-formylation of secondary amines and anilines: Tetrahedron Lett., 41, 9149 (2000).
  • Widely used as a hydrogen donor in catalytic hydrogen transfer reductions. Review: Synthesis, 91 (1988). See also Palladium, A12012, Cyclohexene, A11359, Hydrazine monohydrate, A14005, Formic acid, A13285 and Sodium hypophosphite monohydrate, A13385.
  • Short: III/5a
  • A simple microwave-assisted method for catalytic transfer hydrogenation in ethylene glycol or 1,3-propanediol has been reported: J. Org. Chem., 64, 5746 (1999).
  • Examples include:
  • Reduction of aryl nitro groups to amines: Tetrahedron Lett., 25, 3415 (1984). For reductive cyclization of an o-nitrobenzyl ketone to an indole, see: Org. Synth. Coll., 9, 601 (1998). Hydrogenolysis of N-benzyl groups: Synthesis, 53 (1987); Tetrahedron Lett., 28, 515 (1987). Reduction of aldehydes and ketones to methyl and methylene groups: Tetrahedron Lett., 29, 3741 (1988). The temperature- and solvent-dependencies of this type of reaction have been studied: Synth. Commun., 22, 2673, 2683 (1992). Selective reduction of the heterocyclic ring of quinolines and isoquinolines: Synth. Commun., 20, 2815 (1990). Reduction of pyridine N-oxides to piperidines: J. Org. Chem., 66, 5264 (2001). Regioselective reduction of epoxides: J. Org. Chem., 60, 4922 (1995). Ammonium formate was found to be a more active H donor than either sodium formate or formic acid in the catalytic hydrogenolysis of aryl chlorides. For a comparative mechanistic study of this reaction, see: J. Org. Chem., 60, 1347 (1995).
  • Merck:14,523
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