包装 价格 库存 - 促销价
50g      RMB     0
Ammonium formate, eluent additives for LC-MS	甲酸铵,LC-MS添加物

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  • Mol. Formula: HCO2NH4
  • Mol. Weight: 63.06
  • Melting Point: 119-121 °C(lit.)
  • Density: 1.26 g/mL at 25 °C(lit.)
  • TSCA: Yes
  • Solubility: 可溶
  • Stability: 易吸潮
  • Appearance: {Chemicalbook} 无色结晶,熔点11...
Chemical NameAmmonium formate
CAS Number540-69-2
PubChem Substance ID 24873910
MDL NumberMFCD00013103
Synonym
  • 甲酸銨
  • Ameisensäure Ammoniumsalz
  • AMMONIUM FORMIATE
  • AmmoniumFormateAr
  • AMMONIUM FORMATE PURE
  • 甲酸铵盐
  • FORMIC ACID, AMMONIUM
  • AMMONIUMFORMATE,CRYSTAL,REAGENT
  • AMMONIUM FORMATE
  • Ammoniumformate,99%
  • AMMONIUM FORMAT
  • Formic acid, ammonium salt
  • 甲酸铵 溶液
  • 甲酸铵
  • 甲酸 铵盐
EC Number208-753-9
Merck Number14,523
Beilstein Registry Number3625095
Chemical Name Translation甲酸铵
Wiswesser Line NotationVHO &ZH
GHS Symbol
WGK Germany1
Hazard Codes
  • Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment
  • dust mask type N95 (US), Eyeshields, Gloves
  • Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
Signal word
RTECSBQ6650000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition
  • Store at RT.
  • 密封干燥保存。
  • Hygroscopic
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2250 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ZERNAL Zeitschrift fuer Ernaehrungswissenschaft. (Dr. Dietrich Steinkopff Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.) V.1- 1960- Volume(issue)/page/year: 9,332,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 410 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ZERNAL Zeitschrift fuer Ernaehrungswissenschaft. (Dr. Dietrich Steinkopff Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.) V.1- 1960- Volume(issue)/page/year: 9,332,1969
  • 分析冠军国际cmp,从贵金属盐中沉淀碱金属。 缓冲液组分,用于在凝聚胺(polybrene)亲和层析从复杂系统中分离和纯化糖胺(glycosaminoglycans)
  • Merck:14,523 Beilstein: 2,IV,18
  • Reagent for N-formylation of secondary amines and anilines: Tetrahedron Lett., 41, 9149 (2000).
  • Widely used as a hydrogen donor in catalytic hydrogen transfer reductions. Review: Synthesis, 91 (1988). See also Palladium, A12012, Cyclohexene, A11359, Hydrazine monohydrate, A14005, Formic acid, A13285 and Sodium hypophosphite monohydrate, A13385.
  • Short: III/5a
  • A simple microwave-assisted method for catalytic transfer hydrogenation in ethylene glycol or 1,3-propanediol has been reported: J. Org. Chem., 64, 5746 (1999).
  • Examples include:
  • Reduction of aryl nitro groups to amines: Tetrahedron Lett., 25, 3415 (1984). For reductive cyclization of an o-nitrobenzyl ketone to an indole, see: Org. Synth. Coll., 9, 601 (1998). Hydrogenolysis of N-benzyl groups: Synthesis, 53 (1987); Tetrahedron Lett., 28, 515 (1987). Reduction of aldehydes and ketones to methyl and methylene groups: Tetrahedron Lett., 29, 3741 (1988). The temperature- and solvent-dependencies of this type of reaction have been studied: Synth. Commun., 22, 2673, 2683 (1992). Selective reduction of the heterocyclic ring of quinolines and isoquinolines: Synth. Commun., 20, 2815 (1990). Reduction of pyridine N-oxides to piperidines: J. Org. Chem., 66, 5264 (2001). Regioselective reduction of epoxides: J. Org. Chem., 60, 4922 (1995). Ammonium formate was found to be a more active H donor than either sodium formate or formic acid in the catalytic hydrogenolysis of aryl chlorides. For a comparative mechanistic study of this reaction, see: J. Org. Chem., 60, 1347 (1995).
  • Merck:14,523
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