包装 价格 库存 - 促销价
5g       RMB   160
25g      RMB   390
100g     RMB  1580
Tris(dimethylamino)phosphine
三(二甲胺基)膦

COA下载


  • Mol. Formula: C6H18N3P
  • Mol. Weight: 163.20
  • Density: 0.898 g/mL at 25 °C(lit....
  • Refractive index: 1.4640 to 1.4670
  • Boiling Point: 163°C
  • Flash Point: 26°C(lit.)
  • TSCA: Yes
  • Melting Point: -44°C
  • Solubility: 起反应
  • Stability: 对空气敏感;热和湿度敏感
  • Appearance: {Chemicalbook} 无色吸湿性液体。沸...
Chemical NameTris(dimethylamino)phosphine
CAS Number1608-26-0
Synonym
  • hexamethyl phosphorus triamide
  • hexamethyl-phosphoroustriamid
  • 六甲基磷酰三胺
  • 六甲基三氨基膦
  • Hexamethyltriaminophosphine
  • Phosphine, tris(dimethylamino)-
  • Hexamethylphosphorous triamide
  • Hexamethyltriamidophosphite
  • Tri(dimethylamino)phosphine
  • HMPT
  • Hexamethyl-phosphorous triamide
  • TRIS(DIMETHYLAMINO)PHOSPHINE
  • Phosphine, Tris(dimethylamino)-
  • Tris-(dimethylamino)-phosphin
  • hexamethylphosphorous triamide
  • 三(二甲胺基)膦
  • HEXAMETHYLPHOSPHOROUS TRIAMIDE
  • 己甲基亚磷三酰胺
  • Tris(dimethylamino)phosphine; HMPT
  • HEXAMETHYLTRIAMINOPHOSPHINE
  • 六甲基亚磷酰三胺
  • phosphorous acid tris-dimethylamide
  • N,N,N',N',N'',N''-Hexamethyl-phosphorous Triamide
  • Trisdimethylaminophosphorus
  • Hexametapil
  • Hexamethylphosphorous triamide, HMPT
  • Tris(dimethylamino)phosphine,min.98%HMPT
  • 六甲基亚磷酰三胺;三(二甲氨基)膦;六甲基亚磷酰三胺
  • Tris(dimethylamino)-phosphin
  • tris(dimethylamino)phosphane
  • LABOTEST-BB LT00067758
  • HEXAMETHYLPHOSPHOROUS TRIAMIDE, TECH., 8 5%
  • NSC 102707
  • tris(dimethylamino)phosphine
  • HEXAMETHYL PHOSPHORUS TRIAMIDE
  • Hexamethyl-phosphorous Triamide
  • (Me2N)3P HMPT Hexamethyltriamidophosphite Hexamethyltriaminophosphine 六甲基亚磷酰三胺
  • Tris(dimethylamino)phosphine
  • Phosphorous triamide, hexamethyl-
  • ((CH3)2N)3P
  • 六甲氧基邻三胺
  • Phosphoroustriamide,hexamethyl-
  • Tris(dimethylamino)phosphine (may contain precipitate)
  • HEXAMETHYLPHOSPHOROUS TRIAMIDE, 97 %
  • Hexamethylphosphorigsäuretriamid
MDL NumberMFCD00008301
EC Number216-534-4
Beilstein Registry Number4(4)274
PubChem Substance ID 87577088
Reaxys-RN906778
Chemical Name Translation三(二甲胺基)膦
LabNetwork Molecule IDLN00226609
Signal word
  • Danger
  • Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R45 May cause cancer 可能致癌
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R46 May cause inheritable genetic damage 可能引起遗传基因损害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R10 Flammable 易燃
Precautionary statements
  • P308+313 IF exposed or concerned: Get medical advice/attention. 如接触到或有疑虑:求医/就诊。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261305+351+338
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+312+330
  • P337+313 IF eye irritation persists: Get medical advice/attention. 如果眼睛刺激持续:获取医疗咨询/就医。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P302+352+312+362+364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P304+340+312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+351+338+337+313
  • P241+242+243
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H350 May cause cancer 可能致癌
  • H340 May cause genetic defects 可能导致遗传性缺陷
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSTH3390000
Packing GroupIII
UN Number
  • 1993
  • UN 1993 3/PG 3
  • UN1993
Storage condition
  • Store at RT.
  • 储存温度2-8℃
  • 储存温度2-8℃;充氩保存
  • 0-10°C
  • Air Sensitive
  • 0-10
Hazard Codes
  • T
  • T,Xi,Xn
  • Xn
Hazard Class3
TYPE OF TEST : Sex chromosome loss and nondisjunction ROUTE OF EXPOSURE : Oral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 1 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 212,193,1989
TYPE OF TEST : Morphological transformation TEST SYSTEM : Rodent - hamster Kidney DOSE/DURATION : 2500 ug/L REFERENCE : BJCAAI British Journal of Cancer. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants. RG21 2XS, UK) V.1- 1947- Volume(issue)/page/year: 38,418,1978
  • Reagent combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; hydroxyl group activation; dehydrations.
  • Has also been used for a variety of other reductions including that of ozonolysis intermediates: Helv. Chim. Acta, 50, 2387 (1967), and of primary alkyl nitro compounds to nitriles: Synthesis, 36 (1979). Bromohydrins can be converted to alkenes, by reductive elimination from their triflate esters: J. Am. Chem. Soc., 102, 1433 (1980):
  • Reacts with BrCCl3 to give dichloromethylenephosphorane Cl2C=PPh3, which undergoes Wittig reaction with aldehydes to give 1,1-dichloroalkenes, giving better results than the CCl4/PPh3 combination: Tetrahedron Lett., 1237, 1239 (1977); Synthesis, 554 (1980). Similarly, with Br2CF2, the CF2 group can be transferred to both aldehydes and ketones: J. Fluorine Chem., 1, 123 (1971); Synth. Commun., 3, 197 (1973).
  • Reduces aromatic aldehydes to symmetrical epoxides in good yield: J. Am. Chem. Soc., 85, 1884 (1963). Both cis- and trans-isomers are formed. For list of examples, see: Org. Synth. Coll., 5, 358 (1973). Under suitable conditions, reaction of the intermediate with a second aldehyde can lead to mixed deoxybenzoins or diaryl enamines: Synthesis, 225 (1991).
  • Ryu, H., et al.: J. Mat. Sci., 41, 8265 (2006),
  • Short: II/2
  • Short: II/25D
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。