包装 价格 库存 - 促销价
25g      RMB    40
100g     RMB    70
500g     RMB   180
Triphenylphosphine
三苯基膦

COA下载


MSDS下载


  • Mol. Formula: C18H15P
  • Mol. Weight: 262.29
  • Density: 1.132
  • Vapor Density: 9 (vs air)
  • Boiling Point: 377
  • Vapor Pressure: 5 mmHg ( 20 °C)
  • Melting Point: 79-81
  • Flash Point: 181°(358°F)
  • TSCA: Yes
  • Solubility: Soluble in ether, aceton...
  • Stability: 对光敏感
Chemical NameTriphenylphosphine
MDL NumberMFCD00003043
CAS Number603-35-0
EC Number210-036-0
Beilstein Registry Number610776
Synonym
  • 三酚苯酯
  • TRIPHENYLPHOSPHINE, REAGENTPLUS, 99%
  • PP-360
  • Formylmethylene triphenylphosphorane
  • 三苯膦
  • 三苯基瞵
  • 瞵化三苯基
  • triphenyl-phosphin
  • Phosphorustriphenyl
  • Dehydrocholic acid CP2000
  • Trifenylfosfin
  • Triphenylphosphane
  • 三苯基膦
  • Trihenylphosphine
  • 三苯(基)磷
  • 三苯基膦, POWDER
  • Triphenylphosphine
  • TRP
  • phosphine,triphenyl
  • triphenyl-phosphane
  • 三苯基磷,三苯膦
  • Triphenylphosphide
  • TRIPHENYL PHOSPHOROUS
  • TRIPHENYLPHOSPHINE REAGENTPLUS(TM) 99%
  • Phosphine,triphenyl-
  • 三苯基膦, FLAKE
  • Triphenylphosphorus
  • PHOSPHORUSTRIPHENYL
  • PP 360
  • Triphenyphosphine
Merck Number9743
PubChem Substance ID 24900530
Chemical Name Translation三苯基膦
Reaxys-RN610776
Wiswesser Line NotationRPR&R
LabNetwork Molecule IDLN00198869
Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37 Wear suitable gloves 戴适当手套;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R48/20/22
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261305+351+338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P301+312+330
  • P302+350 IF ON SKIN: Gently wash with plenty of soap and water. 如果在皮肤上:轻轻地用大量肥皂和水清洗
  • P337+313 IF eye irritation persists: Get medical advice/attention. 如果眼睛刺激持续:获取医疗咨询/就医。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P273280
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+352+333+313+362+364
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P304+340+312
Hazard statements
  • H302+332
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment
  • dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSSZ3500000
Hazard Codes
  • Xn
Storage condition
  • 充氮密封保存。
  • Store at RT.
  • 充氮密封避光保存。
UN Number
Warnings
  • 危化品目录(2015)
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1135 ppm/4H TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain REFERENCE : AIHAM* Annual Meeting of American Industrial Hygiene Association. (Akron, OH) For publisher information, see AIHAAP. Volume(issue)/page/year: -,-,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 3 gm/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold REFERENCE : EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0384-0014
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : >500 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Tech
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 700 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold REFERENCE : EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Subs
Packing GroupIII
  • 用于冠军国际betcmp官方网站合成,聚合引发剂,抗菌素类药物氯洁霉素的原料,冠军国际betcmp官方网站微量分析测定磷的标准样品。
  • Azides can be converted selectively to amines, in the presence of ester, epoxide or nitro groups, by reduction to iminophosphoranes (Staudinger reaction), followed by hydrolysis. For reviews, see: Tetrahedron, 37, 437 (1981); 48, 1353 (1992):
  • Finds widespread use as a complexing agent with transition metals, either in the preparation of stable complexes, or as an additive in metal-promoted reactions. See also Tri(o-tolyl)­phosphine, A12093 and Tri(2-furyl)­phosphine, L13329.
  • For use in peptide and other coupling reactions, see 2,2'-Dipyridyl­ disulfide, A11118.
  • In suitable circumstances, the iminophosphorane may undergo intramolecular aza-Wittig reaction: Tetrahedron, 45, 6375 (1989):
  • Reviews: Aza-Wittig reaction in heterocyclic synthesis: Org. Prep. Proced. Int., 24, 209 (1992); Iminophosphoranes as building blocks for the preparation of N-containing heterocycles: Synthesis, 1197 (1994).
  • Merck: 14,9743 Beilstein:16,759
  • Merck: 14,9743
  • For use in the Mitsunobu reaction for conversion of alcohols to alkylating agents, see N-Guanyl­urea sulfate, A19106, and Diisopropyl­ azodicarboxyl­ate, L10386. See also 1,2-Bis(diphenyl­phosphino)­ethane, A11419.
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。