包装 价格 库存 - 促销价
5g       RMB    50
25g      RMB   110
100g     RMB   310
Triisopropylchlorosilane
三异丙基氯硅烷

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  • Mol. Formula: C9H21ClSi
  • Mol. Weight: 192.80
  • Density: 0.901
  • Refractive index: 1.4520 to 1.4540
  • Flash Point: 62°C(lit.)
  • TSCA: No
  • Boiling Point: 96°C/18mmHg(lit.)
  • Vapor Pressure: 1.16 mmHg ( 20 °C)
Chemical NameTriisopropylchlorosilane
MDL NumberMFCD00009656
Synonym
  • 三异丙基氯甲硅烷
  • Triisopropylsilyl chloride Chlorotriisopropylsilane
  • Chlorotriisopropylsilane, 97+%
  • TIPSCI
  • TRIISOPROPYLSILYL CHLORIDE
  • TIPSCl
CAS Number13154-24-0
Beilstein Registry Number1737446
PubChem Substance ID 87576875
EC Number250-023-7
Alfabeta NameTRIISOPROPYLSILYLCHLORIDE
Reaxys-RN1737446
Chemical Name Translation三异丙基氯硅烷
InChIKeyKQIADDMXRMTWHZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007870
Packing GroupII
UN Number
  • UN 2987 8/PG 2
  • UN2987
  • 2987
Risk Statements
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护;
Storage condition
  • Moisture Sensitive
GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261305+351+338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280305+351+338310
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+351+338+310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+330+331+310
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P304+340+310
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P303+361+353+310+363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
Signal word
Hazard Codes
  • C
Warnings
  • IRRITANT
Hazard Class8
RTECSMB9865000
  • For a comprehensive review of the TIPS group in organic chemistry, see: Chem. Rev., 95, 1009 (1995). See also Triisopropyl­silyl­ trifluoromethanesulfonate, B21127.
  • Cleavage is usually accomplished by treatment with F-: J. Org. Chem., 51, 4941 (1986); see Tetra-n-butyl­ammonium fluoride, A10588. Alternative methods include dilute HCl: Tetrahedron Lett., 2865 (1974), or 80% AcOH: J. Carbohydr., Nucleosides, Nucleotides, 3, 197 (1976).
  • Reagent for the protection of alcohols as triisopropylsilyl (TIPS) ethers. See Appendix 4. Methods of introduction include imidazole in DMF: Tetrahedron Lett., 2865 (1974), or imidazole/DMAP: Chem. Lett., 41 (1987). Also useful for N-protection. The steric bulk of TIPS makes it useful as a regio- and stereodirecting group, allowing selective protection of primary hydroxyl in the presence of secondary: Tetrahedron Lett., 2865 (1974). TIPS ethers are more resistant to acidic hydrolysis than TBDMS ethers, but less so than tert-butyldiphenylsilyl (TBDPS) ethers. However, they are more resistant to basic hydrolysis than either TBDMS or TBDPS derivatives: J. Org. Chem., 45, 4797 (1980); 49, 3239 (1984); Tetrahedron Lett., 24, 3455 (1983).
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