包装 价格 库存 - 促销价
10mL     RMB   170
50mL     RMB   490
100mL    RMB   870
Allyltrimethylsilane	烯丙基三甲基硅烷

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  • Mol. Formula: C6H14Si
  • Mol. Weight: 114.26
  • Density: 0.719
  • Refractive index: 1.4060 to 1.4080
  • Flash Point: 7°C(lit.)
  • TSCA: Yes
  • Boiling Point: 84-88
  • Solubility: 不溶
  • Appearance: {Chemicalbook} 无色液体。沸点44...
Chemical NameAllyltrimethylsilane
Synonym
  • 3-TRIMETHYLSILYL-1-PROPENE
  • TRIMETHYLALLYLSILANE
  • Trimethylallylsilane
  • 3-(TRIMETHYLSILYL)PROPENE
  • CA0570
  • Allyltrimethylisilane
  • 丙烯基三甲基矽烷
  • Silane,trimethyl-2-propenyl-
  • Silane, allyltrimethyl-
  • ALLYLTRIMETHYLSILANE
  • trimethylpropenylsilane
  • 3-(Trimethylsilyl)-1-propene
  • 3-(三甲基甲硅烷基)丙烯
  • Allyltrimethylsilian
  • 三甲基烯丙基硅烷,3-(三甲基甲硅烷基)丙烯
  • allyltrimethylsilane
MDL NumberMFCD00008635
CAS Number762-72-1
EC Number212-104-5
Beilstein Registry Number4(3)1854
PubChem Substance ID 87562275
Reaxys-RN906755
Chemical Name Translation烯丙基三甲基硅烷
LabNetwork Molecule IDLN00008514
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S37 Wear suitable gloves 戴适当手套;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
Precautionary statements
  • P210261305+351+338
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261305+351+338
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P301+312+330
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P302+352+312+362+364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
  • P304+340+312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P305+351+338+337+313
  • P241+242+243
  • P233 Keep container tightly closed. ?保持容器密闭。
Packing GroupII
UN Number
  • UN 1993 3/PG 2
  • 1993
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
  • F;Xi
Hazard Class3
Storage condition
  • 0-6°C
  • 用于高分子冠军国际betcmp官方网站硅化合物的合成
  • Has also been used, in the presence of a catalyst such as p-TsOH, I2, Br2 or TfOH, as a silylating agent for alcohols, phenols and carboxylic acids: Tetrahedron Lett., 21, 835 (1980); J. Org. Chem., 46, 5212 (1981). The advantage over more conventional silylation methods is that the only by-product is the neutral gas propene.
  • Reactions with electrophiles illustrate the ß-effect (see Appendix 4); e.g. acid chlorides with a Lewis acid give allyl ketones: J. Organomet. Chem., 85, 149 (1975):
  • Short: III/35C4
  • More recent studies have shown that TMS cyclopentanes are also formed in these reactions via a competing [3+2] cycloaddition mechanism: Tetrahedron, 49, 9955 (1993). Chemoselective addition to aldehydes can be accomplished in the presence of a ketone, using Scandium(III)­ trifluoromethanesulfonate hydrate, 40566 as catalyst: Synthesis, 1822 (1998).
  • In the presence of F-, functions as an allyl anion equivalent, affording homoallylic alcohols from carbonyl compounds: Tetrahedron Lett., 3043 (1978), and adding to a variety of Michael acceptors: Tetrahedron Lett., 25, 3213 (1984); J. Org. Chem., 51, 1745 (1986). For a review of reactivity in the presence of Lewis acids and F-, see: J. Prakt. Chem./ Chem. Ztg., 336, 375 (1994).
  • Similarly, carbonyl compounds are converted to homoallylic alcohols: J. Organomet. Chem., 69, C15 (1974). In the TiCl4 promoted reaction with enones, behaves as an allyl anion equivalent, giving the product of conjugate addition (Hosomi-Sakurai reaction): J. Am. Chem. Soc., 99, 1673 (1977); 105, 2354 (1983); Org. Synth. Coll., 7, 443 (1990):
  • Merck: 14,10335
  • Short: III/35F
  • Merck: 14,10335 Beilstein:4(3)1854
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。