R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性R14 Reacts violently with water 遇水会猛烈反应R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒R10 Flammable 易燃R62 Possible risk of impaired fertility 有削弱生殖能力的危险R21 Harmful in contact with skin 与皮肤接触有害R11 Highly flammable 非常易燃R63 Possible risk of harm to the unborn child 可能危害未出生婴儿R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官R34 Causes burns 会导致灼伤R48/20 R24 Toxic in contact with skin 与皮肤接触有毒R50/53 R51/53
TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 20 ppm/7H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes
Skin and Appendages - dermatitis, other (after systemic exposure)
Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 2541 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E.
First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year:
42,417,1977
⑴.常温常压下为无色发烟液体或气体，有强烈臭味，易潮解。对眼睛、皮肤、粘膜和上呼吸道有强烈的腐蚀作用。吸入后可因喉、支气管的痉挛、水肿，化学性肺炎、肺水肿而致死。中毒表现有烧灼感、咳嗽、喘息、喉炎、气短、头痛、恶心和呕吐。
⑵. 化学反应活性很高，遇水分解生成氯化氢和硼酸，并放出大量热量。在湿空气中因水解而生成烟雾。与铜及其合金有可能生成具有爆炸性的氯乙炔。遇潮气时对大多数金属有强腐蚀性，也能腐蚀玻璃等。三氯化硼反应能力较强，能形成多种配位化合物，具有较高的热力学稳定性，但在放电作用下，会分解形成低价的
用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。
1. Kawaguchi, M. et al. Chem. Mater. 8 , 1197, (1996)
2. McGinnis, M.B. et al. J. Org. Chem. 61 , 3496, (1996)
Merck 14 ,1348
Fieser 1 ,67 / Fieser 2 ,34 / Fieser 3 ,31 / Fieser 4 ,42 / Fieser 5 ,50 / Fieser 6 ,65 / Fieser 9 ,62 / Fieser 12 ,65 / Fieser 13 ,43 / Fieser 14 ,54 / Fieser 15 ,44
Short: II/25A
Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules
Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
Editor: Kuchitsu, K.
Source: Landolt-Börnstein, New Series
Volume: II/25A
Year: 1998
Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules
ISBN: 3-540-61713-2
ISBN: 978-3-540-61713-6
Internet Resource: DOI:10.1007/b59072
RefComment: VII, 359 pages. Hardcover
Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
Short: III/20a
Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl
Author: Chihara, H.; Nakamura, N.
Editor: Hellwege, K.-H.; Hellwege, A.M.
Source: Landolt-Börnstein, New Series
Volume: III/20a
Year: 1988
Keyword: NQR
ISBN: 3-540-18161-X
ISBN: 978-3-540-18161-3
Internet Resource: DOI:10.1007/b31153
RefComment: IX,677 pages. Hardcover
Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and s
