包装 价格 库存 - 促销价
5g       RMB    70
25g      RMB   190
100g     RMB   650
Tri(o-tolyl)phosphine
三(邻甲苯基)膦

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  • Mol. Formula: C21H21P
  • Mol. Weight: 304.37
  • Density: 1.589
  • Melting Point: 124.0 to 129.0 deg-C
  • TSCA: Yes
  • Boiling Point: 238
  • Appearance: {Chemicalbook} 白色晶体
Chemical NameTri(o-tolyl)phosphine
CAS Number6163-58-2
Alfabeta NameTRITOLYLPHOSPHINE M()-
MDL NumberMFCD00008514
Synonym
  • Phosphine, tris(2-methylphenyl)-
  • 三(2-甲苯基)膦
  • TRI-2-TOLYLPHOSPHINE
  • tris(2-methylphenyl)-phosphin
  • Tri-o-tolylphosphine
  • Tri(o-tolyl)-phosphin
  • Tris(2-methylphenyl)phosphine
  • Tris(o-tolyl)phosphine
  • TRIS(O-TOLYL)PHOSPHINE (TOTP)
  • 三邻甲苯基磷
  • Tris(o-toIyl)phosphine
  • 三甲苯磷酸
  • TRI-O-TOLYPHOSPHINE
  • tris(2-methylphenyl)phosphine
  • Tri(o-tolyl)phosphine,98+%
  • TRIS(O-TOLYL)PHOSPHINE
  • Tri(2-methylphenyl)phosphine
  • P(o-tol)3 三(2-甲苯基)膦
EC Number228-193-9
Beilstein Registry Number661212
PubChem Substance ID 87576828
Reaxys-RN661212
Chemical Name Translation三(邻甲苯基)膦
InChIKeyCOIOYMYWGDAQPM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00173237
Warnings
  • IRRITANT
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+352+332+313+362+364
  • P305+351+338+337+313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment
  • dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
  • Xi
  • 配体,用于钌催化的醇的氨基化反应。
  • Short: III/10b
  • Short: EINECS
  • Preferred phosphine ligand for use in combination with Pd salts in the Heck-type coupling reactions of vinylic halides. For examples, see Palladium(II)­ acetate, 10516. For a review of the Heck reaction, see: Org. React., 27, 345 (1982).
  • The Pd-catalyzed amination of bromoarenes with 1-Boc-piperazine, L13363, in the presence of this ligand, provides a route to arylpiperazines of potential pharmacological interest: Tetrahedron Lett., 39, 2219 (1998).
  • Beilstein: 16,III,835
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。