包装 价格 库存 - 促销价
1g       RMB    90
5g       RMB   270
25g      RMB  1140
Tri(2-furyl)phosphine	三(2-呋喃基)磷化氢

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  • Mol. Formula: C12H9O3P
  • Mol. Weight: 232.17
  • Melting Point: 59-64 °C(lit.)
  • TSCA: No
  • Boiling Point: 136 °C/4 mmHg(lit.)
  • Density: 1.422
  • Flash Point: 136°C/4mm
Chemical NameTri(2-furyl)phosphine
CAS Number5518-52-5
Synonym
  • Tri-2-furanylphosphine
  • Tri-furan-2-yl-phosphane
  • Tris(2-furanyl)phosphine
  • Tris(2-furyl)phosphine
  • TRI(2-FURYL)PHOSPHINE
  • Tri(2-furyl)phosphine
  • Tri(2-furanyl)phosphine
  • 三(2-呋喃基)膦
  • TFP Tri-2-furanylphosphine Tris(2-furanyl)phosphine Tris(o-furyl)phosphine
MDL NumberMFCD00151857
EC Number000-000-0
Beilstein Registry Number1577564
PubChem Substance ID 24863985
Chemical Name Translation三(2-呋喃基)磷化氢
Reaxys-RN1577564
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word
  • Warning
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+352+332+313+362+364
  • P261305+351+338
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P305+351+338+337+313
  • P302+350 IF ON SKIN: Gently wash with plenty of soap and water. 如果在皮肤上:轻轻地用大量肥皂和水清洗
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment
  • dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
  • Xi
  • 磷化氢配体,用于过渡金属介入的冠军国际betcmp官方网站合成; 也用于Wittig 反应。
  • In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.
  • Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).
  • Short: III/35C4
  • Beilstein:18(5)12,505
  • Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).
  • Andersen N.G. et al.: Chem. Rev., 101, 997 (2001); Appel M. et al.: Eur. J. Org. Chem., 1143, (2002);
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。