易制爆危险化学品
Potassium permanganate, solution 0,2 mol/l (1 N)	高锰酸钾滴定液,0.2mol/l

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  • Mol. Formula: KMnO4
  • Mol. Weight: 158.03
  • Density: 1 g/mL at 25 °C
  • Melting Point: 240° dec.
  • TSCA: Yes
  • Solubility: Partially soluble in wat...
  • Stability: 对湿度敏感
  • Appearance: {Chemicalbook} {Chemic...
Chemical NamePotassiumPermanganate
MDL NumberMFCD00011364
CAS Number7722-64-7
EC Number231-760-3
Merck Number14,7655
PubChem Substance ID 24859164
Synonym
  • PERMANGANIC ACID POTASSIUM SALT
  • Permanganic acid, potassium salt
  • Permanganate of potash
  • diverseydiversolcxu
  • Cairox
  • KMnO4
  • Chameleon mineral
  • POTASSIUM MANGANATE (VII)
  • 高锰酸钾(药用)
  • Condy's crystals
  • Potassium (permanganate de)
  • Kaliumpermanganat
  • 高锰酸钾
  • Permanganic acid (HMnO3) potassium salt
  • argucide
  • Potassium permanganate
  • chlorisol
  • Permanganic acid potassium salt
  • C.I. 77755
  • icc237disinfectant,sanitizer,destainer,anddeodorizer
  • chameleonmineral
  • BETZ 0263
  • POTASSIUM PERMANGANATE
  • caswellnumber699
  • epapesticidechemicalcode068501
  • diverseydiversolcxwitharodyne
  • ci77755
  • 过锰酸钾
  • 高锰酸钾标准溶液, 0.1N STANDARDIZED SOLUTION
  • 灰锰氧,过锰酸钾
  • c.i.77755
  • Potassium manganate (KMnO4)
  • Permanganate de potassium
  • 高锰酸钾; 过锰酸钾
  • Permanganic acid (HMnO4), potassium salt
  • cairox
  • hilco#88
  • Pure Light E 2
  • Condy's crystals
  • kaliumpermanganaat
  • 高锰酸钾,溶液(0.1N)
  • 灰锰氧
  • 高锰酸钾 溶液
  • 高锰酸钾, ACS, 99.0% MIN
  • Insta-perm
  • 過錳酸鉀
  • algae-k
  • Manganese potassium oxide (KMnO4)
  • KALII PERMANGANAS
  • 高锰酸钾, LOW IN MERCURY, ACS, 99.0% MIN
  • condy’scrystals
  • 灰锰氧;过锰酸钾
  • Potassio (permanganato di)
  • 高錳酸钾 POTASSIUM PERMANGANATE
Chemical Name Translation高锰酸钾
Wiswesser Line NotationKA MN-O4
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H302 Harmful if swallowed 吞食有害
WGK Germany2
Personal Protective Equipment
  • Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
  • dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
  • Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECSSD6475000
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
UN Number
  • UN1490
  • 1490/1482
  • UN 3082 9/PG 3
Risk Statements
  • R52/53
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R51/53
  • R50/53
  • R22 Harmful if swallowed 吞咽有害
Storage condition
  • Light Sensitive
  • 密封保存。
  • Store at RT.
Hazard Codes
  • O,N
  • O;Xn;N
  • N
  • O,Xn,N
Signal word
  • Danger
  • Warning
Packing GroupII
Hazard Class5.1
Restrict
  • 易制毒化学品
Restrict
  • 易制爆危险化学品
Warnings
  • 危化品目录(2015)
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Human - woman DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Vascular - BP lowering not characterized in autonomic section Liver - hepatitis (hepatocellular necrosis), diffuse Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) REFERENCE : HETOEA Human & Experimental Toxicology. (Macmillan Press Ltd., Brunel Road, Houndmills, Basingstoke, Hampshire, RG21 2XS, UK) V.9- 1990- Volume(issue)/page/year: 15,259,1996
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 1151 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 36(9),15,1971
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Human DOSE/DURATION : 143 mg/kg TOXIC EFFECTS : Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - other changes REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,493,1969
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 31,855,1980
TYPE OF TEST
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TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 625 ug/well REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 133,161,1984
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Microorganism - not otherwise specified DOSE/DURATION : 10 ppm REFERENCE : JOBAAY Journal of Bacteriology. (American Soc. for Microbiology, 1913 I St., NW, Washington, DC 20006) V.1- 1916- Volume(issue)/page/year: 54,767,1947
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 10 uL/tube REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 260,295,1991
TYPE OF TEST : DNA adduct TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 200 umol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 89,95,1981
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - mouse Mammary gland DOSE/DURATION : 1 mmol/L/48H REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 67,221,1979
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Oral TEST SYSTEM : Rodent - mouse DOSE/DURATION : 718 mg/kg/7D (Continuous) REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 240,159,1990
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intratesticular SPECIES OBSERVED : Rodent - rat DOSE : 400 mg/kg SEX/DURATION : male 1 day(s) pre-mating TOXIC EFFECTS : Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females) REFERENCE : FESTAS Fertility and Sterility. (American Fertility Soc., 608 13th Ave. S, Birmingham, AL 35282) V.1- 1950- Volume(issue)/page/year: 24,884,1973
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intratesticular SPECIES OBSERVED : Rodent - gerbil DOSE : 25 mg/kg SEX/DURATION : male 1 day(s) pre-mating TOXIC EFFECTS : Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females) REFERENCE : IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 14,617,1976
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE : 513 mg/kg SEX/DURATION : male 5 day(s) pre-mating TOXIC EFFECTS : Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 240,159,1990
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  • The oxidizing power of permanganate can be varied according to the pH of the reaction medium, the use of co-reagents, phase-transfer catalysis, etc. For a comprehensive review of permanganate oxidations in organic chemistry, with particular emphasis on novel applications, see: Synthesis, 85, (1987).
  • For phase-transfer oxidation, catalyzed by Tetra-n-butyl­ammonium hydrogen sulfate, A14047, of unfunctionalized benzylic methylenes, or benzylic alcohols to carbonyls, see: Synthesis, 915 (1987). Similar transformations have been carried out in the presence of triethylamine: Synthesis, 293 (1989).
  • In combination with CuSO 4, has been used as a reagent for the heterogeneous oxidative cyclization of the primary position of a primary-secondary diol to the lactone: J. Chem. Soc., Chem. Commun., 634 (1988); Org, Synth. Coll., 9, 462 (1998):
  • Merck: 14,7655
  • For phase-transfer assisted oxidation of primary amines to azo compounds, see: Bull. Soc. Chim. Belg., 102, 59 (1993).
  • In combination with TMS chloride
  • Classical permanganate cleavage of olefins is difficult to control, and normally proceeds to the highest possible oxidation level. Adsorption of the reagent on moist alumina has been found to attenuate its activity and allow good yields of aldehydes to be obtained. This would appear to provide a possible alternative to ozonolysis for this conversion: J. Org. Chem., 58, 2918 (1993). For use in the cis-hydroxylation of olefins, see Dicyclohexano-18-crown-6, A15344.
  • For the use of (1-Hexadecyl)­trimethyl­ammonium bromide, A15235, as a surfactant in permanganate oxidations in micelles, see: Can. J. Chem., 67, 1381 (1989).
  • In combinat
  • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。